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Semester 1, Academic Year 1998/1999 Section C

Question 14

A liquid mixture of benzene-toluene is to be continuously separated in a distillation column operating at 101.3 kPa. The feed flow rate is 100 kg-mole/hr and enters the column at its bubble point. It contains 45 mole% benzene and 55 mole% toluene. A distillate containing 95 mole% benzene and a bottoms containing not more than 10 mole% benzene are to be obtained. The reflux ratio used is 2 times the minimum reflux ratio Rmin .

Determine:

(a) Distillate and bottoms flow rates in kg-mole/hr

( 6 marks )

(b) Minimum reflux ratio Rmin

( 7 marks )

(c) Number of theoretical trays needed

( 7 marks )


Equilibrium curve for benzene-toluene system at 101.3 kPa is given below:

Equilibrium curve for benzene-toluene system

Question 15


A counter-current gas absorption column is to be designed to absorb SO2 from an air-SO2 mixture using pure water at 293 K. The column is to be operated at 293 K and 101.3 kPa.

Laboratory analysis showed that the gas entering the column contains 20 mole% SO2 and environmental regulations require that the gas leaving the column contains no more than 2 mole% SO2. The inert air (MW = 29) flow rate is 150 kg air/m2.hr, and the entering pure water (MW = 18) flow rate is 6000 kg water/m2.hr.

If the overall tray efficiency is 25%, determine the actual number of trays required for the separation.

( 20 marks )

Equilibrium data for SO2-water system at 101.3 kPa are given below:

Solubility data for SO2 in Water

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